Improvement of 12 V overcharge behavior of LiCoO2 cathode material by LiNi0.8Co0.1Mn0.1O2 addition in a Li-ion cell

Autor: Jaephil Cho, Jisuk Kim, Mijung Noh
Rok vydání: 2006
Předmět:
Zdroj: Journal of Power Sources. 153:345-349
ISSN: 0378-7753
DOI: 10.1016/j.jpowsour.2005.05.035
Popis: The 12 V overcharge instability of the LiCoO2 cathode material was improved by the physical blending it with LiNi0.8Co0.1Mn0.1O2. Even though a Li-ion cell containing a LiCoO2 cathode did not exhibit thermal runaway at 12 V at the 1 C overcharging rate, it showed thermal runaway at the 2 C overcharging rate, and the cell surface temperature reached more than 400 °C. However, the LiCoO2 cell containing 40, 50, and 60 wt.% LiNi0.8Co0.1Mn0.1O2 did not exhibit thermal runaway at the 2 C overcharging rate. In conclusion, 60 wt.% LiNi0.8Co0.1Mn0.1O2 in the LiCoO2 cathode showed the lowest cell surface temperature of
Databáze: OpenAIRE