Unusual behaviour of a new kind of side chain crown ether polysiloxanes used in capillary gas chromatography

Autor:	Wei Zhou, Ruonong Fu, Zaifu Huang, Rongji Dai, Peng. Jing, Yanfei Chen
Rok vydání:	1996
Předmět:	chemistry.chemical_classification Phase transition Chromatography Chemistry Organic Chemistry General Medicine Biochemistry Capillary gas chromatography Analytical Chemistry Stationary phase Benzene derivatives Side chain Organic chemistry Gas chromatography Crown ether
Zdroj:	Journal of Chromatography A. 752:189-195
ISSN:	0021-9673
Popis:	A new side chain crown ether polysiloxane (PSCP-3-15C5) has been prepared and characterized in chromatography. Its chromatographic behaviour was compared with that of the other side chain crown ether polysiloxane (PSCP-11-15-C5), which has a longer spacer. The unusual effects caused by the length of the spacer on the polysiloxane backbone are described. An interesting phenomenon, liquid-liquid transition occurring in the measurement of phase transition on PSCP-3-15-C5, is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ff102f7dffe77efc9877fbc7f654715b https://doi.org/10.1016/s0021-9673(96)00479-7 Zobrazit plný text záznamu Full Text from ScienceDirect