Advancing Sustainable Manufacturing through a Heterogeneous Cobalt Catalyst for Selective C–H Oxidation
| Autor: | Aaron J. Bloomfield, Paul T. Anastas, Samuel L. Collom |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Chemical transformation 010405 organic chemistry General Chemical Engineering Sustainable manufacturing chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Industrial and Manufacturing Engineering 0104 chemical sciences Catalysis Cobalt catalyst chemistry.chemical_compound chemistry Catalytic oxidation Organic chemistry Cobalt Phosphine Alkyl |
| Zdroj: | Industrial & Engineering Chemistry Research. 55:3308-3312 |
| ISSN: | 1520-5045 0888-5885 |
| DOI: | 10.1021/acs.iecr.5b03674 |
| Popis: | An increasingly important chemical transformation that will be necessary as we move toward sustainable manufacturing is the oxidation of C–H bonds. Our reported robust heterogeneous cobalt water oxidation catalyst, formed from a metal carbonyl phosphine complex as precursor, is now shown to be active for the selective oxidation of C–H bonds. Of 10 oxidants tested, only Oxone and its oxidatively active component KHSO5 proved competent. A wide variety of substrates were effectively oxidized with KHSO5, including heterocycles, alkyl arenes, alcohols, alkenes, and alkanes. The catalyst is highly selective for C–H bonds over water oxidation when the reaction is conducted in aqueous media. The catalyst can be recycled with minimal loss of activity while under N2. Preliminary mechanistic data are also discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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