ChemInform Abstract: A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes

Autor:	Chao Liu, Qing-Yun Chen, Yong Guo, Ji-Chang Xiao, Dong‐Fang Jiang
Rok vydání:	2015
Předmět:	chemistry.chemical_compound chemistry Ether General Medicine Combinatorial chemistry
Zdroj:	ChemInform. 46
ISSN:	0931-7597
Popis:	A mild method of converting arylamines into perfluoroalkylated arenes is described. Relatively stable RFCu(CH3CN) complexes are used as perfluoroalkylating agents, which react smoothly with arenediazonium salts to produce various perfluoroalkylarenes in good yields. Based on the results of clock trapping experiments with diallyl ether, a radical process might be involved in the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fef42588342c41dceae0d518ba4518aa https://doi.org/10.1002/chin.201512086 Zobrazit plný text záznamu Plný text