Radical Behavior of CO2versus its Deoxygenation Promoted by Vanadium Aryloxide Complexes: How the Geometry of Intermediate CO2-Adducts Determines the Reactivity
| Autor: | Ilia Korobkov, Sebastiano Licciulli, Sandro Gambarotta, Camilo J. Viasus, Nicholas P. Alderman |
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| Rok vydání: | 2017 |
| Předmět: |
Ligand field theory
010405 organic chemistry Chemistry Ligand Organic Chemistry Vanadium chemistry.chemical_element Electron donor General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences Adduct chemistry.chemical_compound 13. Climate action Reactivity (chemistry) Deoxygenation Carbon monoxide |
| Zdroj: | Chemistry - A European Journal. 23:17269-17278 |
| ISSN: | 0947-6539 |
| DOI: | 10.1002/chem.201702943 |
| Popis: | The reactivity of carbon dioxide with vanadium(III) aryloxo complexes has been investigated. The formation of either carbon monoxide or incorporation into the ligand system with the ultimate formation of organic ester was observed depending on the overall electron donor ability of the ligand field. DFT calculations were carried out to investigate the proposed mechanism for carbon dioxide coordination and reduction. |
| Databáze: | OpenAIRE |
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