Radical telomerization of vinyltrimethylsilane by bromoform and partial chain-transfer constants

Autor:	B. V. Nelyubin, V. A. Kochetkova, T. T. Vasil'eva, R. Kh. Freidlina
Rok vydání:	1986
Předmět:	Chain transfer General Chemistry Benzoyl peroxide Photochemistry Peroxide Chemical reaction Dissociation (chemistry) chemistry.chemical_compound chemistry Polymerization medicine Bromoform Bond cleavage medicine.drug
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:1270-1273
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00956613
Popis:	1. The telomerization of vinyltrimethylsilane by bromoform initiated by benzoyl peroxide occurs because of scission of the C-Br bond in bromoform and gives telomers of structure CHBr2[CH2CHSiMe3]nBr, where n=1, 2. The first partial chain-transfer constant C1≈120. 2. When the vinyltrimethylsilane/bromoform ratio is ≤5, by-product tetrabromo derivatives CBr3CH2CHBrSiMe3 and CBr2[CH2CHBrSiMe3]2 are formed.
Databáze:	OpenAIRE
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