Amphiphilic iron(ii) complexes with short alkyl chains – crystal packing and spin transition properties

Autor:	Stephan Schlamp, Katja Dankhoff, Birgit Weber
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Spin states Chemistry Stereochemistry Spin transition General Chemistry Crystal structure Catalysis Crystal Crystallography Spin crossover Amphiphile Materials Chemistry Alkyl Stoichiometry
Zdroj:	New J. Chem.. 38:1965-1972
ISSN:	1369-9261 1144-0546
Popis:	An amphiphilic iron(II) spin crossover complex with relatively short octyl chains was synthesised and the crystal structures of the high spin and the low spin state could be determined. In further reactions, a second modification of the hexa-coordinated complex and two different penta-coordinated complexes could be obtained and characterised by X-ray structure analysis. The examples demonstrate an influence of the alkyl chains on the stoichiometry of the final product. Different arrangements of the alkyl chains were observed in the crystal packing. Despite those differences, the spin transition of the hexa-coordinated complexes is always gradual and comparable to that observed in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::feb3ac3bf94b50486368634651644e19 https://doi.org/10.1039/c3nj00991b Zobrazit plný text záznamu