Stability of U(VI) solid phases in the U(VI)-Ca2+-SiO2-OH system

Autor:	A. G. Sowder, Sue B. Clark, H. Neff, C. Phelps, B. Ritherdon
Rok vydání:	2003
Předmět:	Mineral Scanning electron microscope chemistry.chemical_element Calcium Uranyl Silicate chemistry.chemical_compound Crystallography chemistry Solid phases Physical chemistry Uranate Physical and Theoretical Chemistry Uranophane
Zdroj:	Radiochimica Acta. 91:93-96
ISSN:	2193-3405 0033-8230
DOI:	10.1524/ract.91.2.93.19992
Popis:	Synthetic metaschoepite was altered at 70 °C, for 30 days in silicate solutions of varying compositions to study alteration reactions and to compare experimental observations with a thermodynamic model of stability of the uranyl minerals metaschoepite ([(UO2)8O2(OH)12](H2O)10), becquerelite (Ca[(UO2)3O2(OH)3]2(H2O)8), α-uranophane (Ca[(UO2)(SiO3OH)]2(H2O)5) and soddyite ((UO2)2(SiO4)· (H2O)2). Powder X-ray diffraction analysis, scanning electron microscopy and solution chemistry were used to monitor the alteration of the initial metaschoepite. In general, the secondary phases predicted by the thermodynamic model formed. However, an unexpected mineral (a calcium uranate) was observed above pH 8. Also, within the timeframe of these experiments, U(VI) silicate phases only formed at Si concentrations much higher than the lower field boundaries for uranophane and soddyite.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe9e8b6acd5504bb07e0cb4437b5cfa8 https://doi.org/10.1524/ract.91.2.93.19992 Zobrazit plný text záznamu