Thermal decomposition of barium(II) tetraphenylborate

Autor: Zhou Bao-Xue, Wang Xiao-Ling, Zou Li-zhuang, Zhong Wei-ke
Rok vydání: 1996
Předmět:
Zdroj: Journal of Thermal Analysis. 47:815-820
ISSN: 1572-8943
0368-4466
DOI: 10.1007/bf01981816
Popis: Barium(II) tetraphenylborate, Ba(Bph4))2·4H2O was prepared, and its decomposition mechanism was studied by means of TG and DTA. The products of thermal decomposition were examined by means of gas chromatography and chemical methods. A kinetic analysis of the first stage of thermal decomposition was made on the basis of TG and DTG curves and kinetic parameters were obtained from an analysis of the TG and DTG curves using integral and differential methods. The most probable kinetic function was suggested by comparison of kinetic parameters. A mathematical expression was derived for the kinetic compensation effect.
Databáze: OpenAIRE