Development of quadrupolar engaging auxiliaries as novel gearing elements for macrocyclization

Autor:	Yassir El-Azizi, Shawn K. Collins
Rok vydání:	2006
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Olefin fiber chemistry Stereochemistry General Chemical Engineering Non-covalent interactions General Chemistry Metathesis Cyclophane
Zdroj:	Pure and Applied Chemistry. 78:783-789
ISSN:	1365-3075 0033-4545
DOI:	10.1351/pac200678040783
Popis:	The formation of various macrocyclic cyclophanes via ring-closing olefin metathesis is possible through the use of a pendant pentafluorobenzyl ester group. A quadrupolar interaction between the cyclophane core and the auxiliary is proposed to act as a gearing element facilitating cyclization. The development of these noncovalent interactions as gearing elements as well as the investigation of the effect of the site of metathesis upon the macrocyclization process is described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe691621b2ae3d79fe0c9ba2d8f1f848 https://doi.org/10.1351/pac200678040783 Zobrazit plný text záznamu