ChemInform Abstract: Selective Reduction of Saturated Perfluorocarbons

Autor:	John Anthony Marsella, Andrew G. Gilicinski, Guido Peter Pez, Anne M. Coughlin
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Perfluorocyclohexane chemistry Sodium Benzophenone Organic chemistry chemistry.chemical_element Selective reduction General Medicine Carbon Ion
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199242103
Popis:	Perfluorocycloaliphatic compounds are reduced by solutions of the sodium benzophenone radical anion to give perfluorinated and highly fluorinated aromatic compounds. Perfluorocycloalkanes containing tertiary carbon centers are much more reactive than perfluorocyclohexane. Reduction of perfluoroalkanes and perfluorocycloalkanes that contain perfluoroalkyl substituents proceeds easily; however, it appears that overreduction occurs and no organofluorine products are obtained with these substrates
Databáze:	OpenAIRE
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