Synthesis and Functional Evaluation of Soy Fatty Acid Methyl Ester Ketals as Bioplasticizers

Autor:	Subbarao Kandula, Michael Grass, Lucas J. Stolp, Benjamin Woldt, Dharma R. Kodali
Rok vydání:	2014
Předmět:	Thermogravimetric analysis Diisononyl phthalate General Chemical Engineering Organic Chemistry Plasticizer Chloride chemistry.chemical_compound Polyvinyl chloride chemistry medicine Acetone Organic chemistry Saponification Fatty acid methyl ester medicine.drug
Zdroj:	Journal of the American Oil Chemists' Society. 91:1967-1974
ISSN:	1558-9331 0003-021X
DOI:	10.1007/s11746-014-2529-8
Popis:	A facile synthesis of the soy fatty acid methyl ester ketal has been accomplished using acetone in the presence of catalytic anhydrous ferric chloride starting from commercially available soy biodiesel (soy fatty acid methyl ester) after evaluating various synthetic procedures. The soy ketal product was fully characterized by nuclear magnetic resonance, infra-red and chromatography. The physical and analytical properties of soy ketal as determined by thermogravimetric analysis, viscosity acid and saponification values are acceptable for plasticizer applications. Soy ketal was compounded with polyvinyl chloride for evaluation of plasticizer properties such as efficiency, gelation, viscosity, volatility, thickening/aging behavior and stability. The thickening and aging behaviors of the soy ketal bioplasticizer are better than those of petroleum-based plasticizers such as diisononyl phthalate and diisononyl-cyclohexane dicarboxylate, but they need improvement in the areas of thermal stability and water extractability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe5a14b8a11a7254af6bb323d84c3e43 https://doi.org/10.1007/s11746-014-2529-8 Zobrazit plný text záznamu Full text from SpringerLink Plný text