Transposition des oximies de la 2H-naptho [1,8-bc] pyrannone-3 et de la 2H-benzo [b] furannone-3
Autor: | Jean-Claude Hardy, Marc Venet |
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Rok vydání: | 1982 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 23:1255-1256 |
ISSN: | 0040-4039 |
Popis: | Refluxing the oximes ( 2 ) of naphtho-[1,8-bc] pyran-3(2H)-one and ( 6 ) of 3 (2H)-benzofuranone with alcoholic hydrogen chloride give the corresponding α-alkoxy-ketones 3 , 4 , 5 and α-chloroketone 7 respectively. This transformation appears to be related to the acid conversion of N-aryhydroxylamines to o. and p. substituted anilines (BAMBERGER rearrangement. |
Databáze: | OpenAIRE |
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