Transposition des oximies de la 2H-naptho [1,8-bc] pyrannone-3 et de la 2H-benzo [b] furannone-3

Autor: Jean-Claude Hardy, Marc Venet
Rok vydání: 1982
Předmět:
Zdroj: Tetrahedron Letters. 23:1255-1256
ISSN: 0040-4039
Popis: Refluxing the oximes ( 2 ) of naphtho-[1,8-bc] pyran-3(2H)-one and ( 6 ) of 3 (2H)-benzofuranone with alcoholic hydrogen chloride give the corresponding α-alkoxy-ketones 3 , 4 , 5 and α-chloroketone 7 respectively. This transformation appears to be related to the acid conversion of N-aryhydroxylamines to o. and p. substituted anilines (BAMBERGER rearrangement.
Databáze: OpenAIRE