The transition state in the carbonyl-forming elimination reaction of alkyl nitrates

Autor:	A. G. Horgan, T. J. George, Y. T. Lin, Harold Kwart
Rok vydání:	1981
Předmět:	chemistry.chemical_classification Proton Base (chemistry) Organic Chemistry Inorganic chemistry Medicinal chemistry Catalysis Chemical kinetics Elimination reaction Deuterium chemistry Kinetic isotope effect Nuclear Experiment Alkyl
Zdroj:	The Journal of Organic Chemistry. 46:1970-1972
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00322a062
Popis:	The title reaction, now found to involve proton tunneling with base catalysis and a cyclic, nonlinear proton transfer in the uncatalyzed gas-phase process, cannot have (as previously formulated) an E/sub CO/2 mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe52c74b86059f349cc8a4b7706a9c82 https://doi.org/10.1021/jo00322a062 Zobrazit plný text záznamu