FT-IR Analysis of the Laser-Induced Dissociation of Methylphosphonic Difluoride

Autor:	Ann E. Stanley
Rok vydání:	1995
Předmět:	Reaction mechanism Infrared Chemistry Difluoride Laser Photochemistry Dissociation (chemistry) Methane law.invention Product analysis chemistry.chemical_compound law Fourier transform infrared spectroscopy Instrumentation Spectroscopy
Zdroj:	Applied Spectroscopy. 49:478-481
ISSN:	1943-3530 0003-7028
DOI:	10.1366/0003702953964219
Popis:	The output of a continuous-wave carbon dioxide laser was used successfully for the dissociation of methylphosphonic difluoride. End product analysis using Fourier transform infrared spectroscopy revealed that the phosphorus-to-carbon bond was cleaved, yielding the products methane, ethene, ethyne, hydrophosphoryl difluoride, and a mixture of phosphorus compounds. These results are presented and discussed. The dissociation was optimized. A reaction mechanism of the dissociation is suggested.
Databáze:	OpenAIRE
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