Synthesis of a new rhodamine-containing block copolymer for highly selective and sensitive detection of Cu2+ and CN− ions in aqueous media

Autor: Rakesh Banerjee, Dibakar Dhara, Deep Sankar Pal
Rok vydání: 2014
Předmět:
Zdroj: Polymer International. 63:1974-1981
ISSN: 0959-8103
DOI: 10.1002/pi.4742
Popis: Development of new chemosensors that are selective and sensitive to Cu2+ and CN− ions, especially in aqueous media, is of tremendous importance. We report the synthesis of a new block copolymer that is capable of highly selective and sensitive detection of Cu2+ and CN− ions in aqueous media. Poly(t-butylacrylate)-block-poly(3-bromopropylacrylate) was prepared using the reversible addition–fragmentation chain transfer polymerization technique. This block copolymer was reacted with 2,4-dihydroxybenzaldehyde followed by reaction with rhodamine B hydrazide for successful incorporation of the desired rhodamine units into the block copolymer structure. Cu2+-induced opening of the spirolactam ring of the rhodamine units resulted in rapid and easily noticeable colour change, thus enabling a highly selective detection of Cu2+ ions in aqueous media for concentrations as low as 2 µmol L−1. We further demonstrate that this Cu2+ bound polymer complex can further act as a selective and sensitive sensing platform for CN− in aqueous media with concentrations
Databáze: OpenAIRE