Nucleophilic addition of glycine esters to Gd@C82

Autor:	Zhennan Gu, Zujin Shi, Xihuang Zhou, Xing Lu
Rok vydání:	2004
Předmět:	Nucleophilic addition Glycine methyl ester Alcohol Mass spectrometry Toluene Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Metallofullerene Glycine Materials Chemistry Organic chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 357:2397-2400
ISSN:	0020-1693
DOI:	10.1016/j.ica.2004.01.042
Popis:	The first investigation of nucleophilic addition of glycine esters to Gd@C 82 is reported and hydroxyl was found to compete with glycine esters in the reaction. The multiple adducts containing either mere glycine esters or both glycine esters and hydroxyl group were identified by MALDI TOF mass spectrometry and characterized with UV–Vis–NIR spectrometry. Because glycine ethyl ester is more soluble than glycine methyl ester in alcohol and toluene, as many as eight glycine ethyl ester groups can be added to the metallofullerene cage while the maximal number for glycine methyl ester groups is only four.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fe3d15398653520dcc80af100751c0f4 https://doi.org/10.1016/j.ica.2004.01.042 Zobrazit plný text záznamu Full Text from ScienceDirect