Epoxidation of tetracyclodecene hydrocarbons with the H2O2·CO(NH2)2 adduct in the presence of heteropoly compounds containing rare-earth metal cations
| Autor: | O. A. Sadygov, E. S. Musaeva, Kh. M. Alimardanov, N. R. Dadashova, M. B. Almardanova, N. I. Garibov |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Cyclopentadiene Bicyclic molecule 010405 organic chemistry Chemistry chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy 010402 general chemistry 01 natural sciences Mordenite 0104 chemical sciences Adduct Metal chemistry.chemical_compound visual_art Polymer chemistry visual_art.visual_art_medium Organic chemistry Carbon Alkyl |
| Zdroj: | Russian Journal of General Chemistry. 87:208-214 |
| ISSN: | 1608-3350 1070-3632 |
| Popis: | Epoxidation of tetracyclododecene bridged hydrocarbons prepared via the [4+2]-condensation of bicyclo[2.2.1]hept-2-ene and its alkyl derivatives with cyclopentadiene in the presence of Н-form of synthetic mordenite has been studied. Phosphorus-molybdenum and phosphorus-tungsten heteropoly compounds doped with Co3+, Gd3+, Nd3+, Ce(4–x)+ (x = 0, 1) cations as well these compounds deposited on highly disperse carbon material have exhibited high activity in epoxidation of the synthesized hydrocarbons under the action of the H2O2·CO(NH2)2 adduct. Structures of the new bridged polycyclic epoxides have been elucidated by IR as well as 1Н and 13С NMR spectroscopy. |
| Databáze: | OpenAIRE |
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