Effect of copper concentration and spray rate on the properties Cu2ZnSnS4 thin films deposited using spray pyrolysis
| Autor: | M. R. Rajesh Menon, K.P. Vijayakumar, C. Sudha Kartha, V.G. Rajeshmon |
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| Rok vydání: | 2014 |
| Předmět: |
Materials science
Band gap Metallurgy chemistry.chemical_element Copper Analytical Chemistry Copper sulfide chemistry.chemical_compound Solution precursor plasma spray Fuel Technology chemistry Chemical engineering Electrical resistivity and conductivity parasitic diseases CZTS Thin film Stoichiometry |
| Zdroj: | Journal of Analytical and Applied Pyrolysis. 110:448-454 |
| ISSN: | 0165-2370 |
| DOI: | 10.1016/j.jaap.2014.10.014 |
| Popis: | Polycrystalline Cu 2 ZnSnS 4 (CZTS) thin films were prepared using chemical spray pyrolysis. We examined the influence of concentration of copper in spray solution and spray rate on the properties of the films. Choice of copper concentration in the precursor solution was found to have a pivotal role in adjusting composition, band gap and resistivity of sprayed CZTS thin films. Nearly stoichiometric CZTS thin films with desirable band gap were obtained by using copper concentration of 0.015 M. Spray rate also has crucial role in adjusting properties like band gap of the films. Higher spray rates resulted in rougher films with secondary phases of copper sulfide. Secondary phases were also observed at low spray rate of 2 ml/min. Good films without any secondary phases and having band gap of 1.5 eV were obtained at the spray rate of 6 ml/min. |
| Databáze: | OpenAIRE |
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