Metal complexes of alkyl pyrazines-I
Autor: | J. W. Wheeler, A. Adeyemo, A. Ben Hussein, Abdullah Shamim, Anne M. Turner, Mah T. Shamim |
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Rok vydání: | 1984 |
Předmět: |
chemistry.chemical_classification
Pyrazine Chemistry Stereochemistry Chemical shift Nuclear magnetic resonance spectroscopy Carbon-13 NMR Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound visual_art Materials Chemistry Mass spectrum visual_art.visual_art_medium Molecule Physical and Theoretical Chemistry Alkyl |
Zdroj: | Inorganica Chimica Acta. 91:179-182 |
ISSN: | 0020-1693 |
Popis: | Pyrazines are an important constituent of plants and insects. We report the synthesis, elemental analysis, mass spectra, 13 C nmr and I.R. studies of Pt(II) complexes of dimethyl pyrazine isomers (DMP). A trend in cluster formation of Pt(II)-DMP complexes is observed. Based on the 13 C chemical shifts, we postulate that in all the complexes Pt-pyrazine bonding is through N-1 rather than N-4. |
Databáze: | OpenAIRE |
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