Optimization of the new technology for manufacturing γ-polyoxymethylene

Autor:	V. M. Zinov’ev, O. A. Gladkova, A. M. Fedoseev
Rok vydání:	2016
Předmět:	Solvent chemistry.chemical_compound chemistry Polymerization Chemical engineering Polyoxymethylene Yield (chemistry) Organic chemistry General Chemistry Particle size Toluene Boron trifluoride Catalysis
Zdroj:	Russian Journal of General Chemistry. 86:1476-1478
ISSN:	1608-3350 1070-3632
Popis:	A new technology of manufacturing γ-polyoxymethylene (γ-POM) by the polymerization 1,3,5-trioxane in the presence of a boron trifluoride etherate aprotic catalytic agent and a methylal telogen in the medium of the non-ozone-depleting solvent toluene, with an yield exceeding the yield of γ-POM manufactured by the existing industrial technology by 30% is developed. Regression equations for the yield and weight-average particle size of γ-POM synthesized in the toluene medium were derived by means of the optimal experimental design technique. The equations were used to optimize parameters of the synthesis and obtain γ-POM with the weight-average particle size of 15 μm and the highest possible yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fdaecb6c79f41cc017535ce56b6288a7 https://doi.org/10.1134/s1070363216060402 Zobrazit plný text záznamu Plný text ve formátu PDF