Mother Diamine: A Universal Building Block for Making Chiral Ligands from Daughter Diamines to Binol, Binap and Monophos Analogues

Autor:	Hyunwoo Kim, Soon Mog So, Jik Chin, An Soo Lee, Alan J. Lough
Rok vydání:	2014
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Diamine Organic Chemistry Asymmetric hydrogenation Reactivity (chemistry) Stereoselectivity Ethylenediamine Reductive amination Highly sensitive BINAP
Zdroj:	Asian Journal of Organic Chemistry. 3:1102-1107
ISSN:	2193-5807
Popis:	“Mother diamine” (MD) or 1,2-bis(2-hydroxy-phenyl)ethylenediamine can be rapidly transformed to a wide variety of chiral ligands including vicinal diamines and analogs of binol (MDdiol), binap (MDdiphos), and monophos (MDphos). The reactivity and stereoselectivity of the MDphos ligands in Rh-catalyzed hydrogenation are highly sensitive to the N,N′-dialkyl substituents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fd9e19bfcfa9b97a8ce6b15261e6967c https://doi.org/10.1002/ajoc.201402135 Zobrazit plný text záznamu Plný text