Doped Polymers by Oxidative Polymerization. 4. Oxidative Coupling of Methylated Oligothiophenes by FeCl3·6H2O as a Model Reaction for the Oxidative Polymerization of Thiophene Derivatives

Autor:	Peter Tschuncky, Gerhard Kossmehl, Gunnar Engelmann, Werner Jugelt, Hans-Peter Welzel, Jürgen Heinze
Rok vydání:	1996
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Doping Oxidative phosphorylation Polymer Photochemistry Thiophene derivatives Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Polymerization Materials Chemistry Molecule Oxidative coupling of methane
Zdroj:	Macromolecules. 29:3370-3375
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma951198o
Popis:	Methylated bi- and terthiophenes (monomers, 1, 3, 5, 8) with one free α-position can be oxidized with FeCl3·6H2O. An irreversible dimerization reaction forms dimers of the expected structure. The r...
Databáze:	OpenAIRE
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