New members of radical bridged Ln2 metallocene single-molecule magnets based on the unsubstituted 1,2,4,5-tetrazine ligand
| Autor: | Niki Mavragani, Alexandros Kitos, Akseli Mansikkamäki, Muralee Murugesu |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Inorganic Chemistry Frontiers. 10:259-266 |
| ISSN: | 2052-1553 |
| DOI: | 10.1039/d2qi02164a |
| Popis: | The combination of the 1,2,4,5-tetrazine (tz) with Ln metallocenes led to a new family of radical-bridged dinuclear complexes. Strong magnetic Ln–rad coupling was observed, which afforded zero-field SMM behavior for the Tb and Dy analogues. |
| Databáze: | OpenAIRE |
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