ChemInform Abstract: Cyclization Reactions of Molybdenum and Chromium Carbene Complexes with Enynes

Autor:	Daniel F. Harvey, David A. Neil, Kevin P. Lund
Rok vydání:	2010
Předmět:	Allylic rearrangement Thermal decomposition Substituent chemistry.chemical_element Ether General Medicine Medicinal chemistry chemistry.chemical_compound Chromium chemistry Molybdenum Yield (chemistry) Organic chemistry Carbene
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199226075
Popis:	Thermolysis of enynes with pentacarbonyl(butylmethoxycarbene)molybdenum (0) 1a produces vinylcyclopropanes in significantly higher yields than the analogous chromium carbene complexes 1b and 3. Additionally, enynes with an allylic ether substituent are shown to cyclize to vinylcyclopropanes in good to excellent yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fd2a66370479d57328d460e9e3a5fb93 https://doi.org/10.1002/chin.199226075 Zobrazit plný text záznamu Plný text