cis,cis - Trialkyl-triaziridines photoelectron spectra - X-ray structural analysis

Autor: Wolfgang Marterer, Horst Prinzbach, Stefan Gries, Otmar Klingler, Christoph Sigwart, Hermann Irngartinger, Rolf Gleiter
Rok vydání: 1988
Předmět:
Zdroj: Tetrahedron Letters. 29:185-188
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80048-9
Popis: PE-analysis of three cis,cis-trialkyltriaziridines ( 1-3 ) reveals a relatively large Jahn-Teller effect (0.4 eV) for the 2 E state and a large split (2.5 eV) between the 2 E and 2 A 1 states indicating a strong interaction between the lone pairs. For a triaziridine (4) the structural parameters are presented (X-ray analysis).
Databáze: OpenAIRE