Aluminum oxide-induced gas-phase ring-opening in methyl substituted gem-difluorocyclopropanes, leading to 2-fluorobuta-1,3-dienes and vinylacetylenes

Autor:	N. V. Volchkov, Maxim A. Novikov, Oleg M. Nefedov, M. B. Lipkind
Rok vydání:	2015
Předmět:	Chemistry General Chemistry Organofluorine compounds Ring (chemistry) Photochemistry Pyrolysis Aluminum oxide Gas phase
Zdroj:	Russian Chemical Bulletin. 64:658-663
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-015-0914-6
Popis:	A gas-phase pyrolysis of methyl-substituted gem-difluorocyclopropanes in a flow-tube reactor in the presence of Al2O3 at 185—250 °C gives 2-fluorobuta-1,3-dienes and vinylacetylenes.
Databáze:	OpenAIRE
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