SYNTHESIS AND STRUCTURAL FEATURES OF SOME FIRST ROW TRANSITION SERIES METAL BIS(BIURET) POLYMERIC CHELATES

Autor:	Harjeet D. Juneja, K. N. Munshi, Sushmita M. Roy
Rok vydání:	2001
Předmět:	Chemistry Inorganic chemistry Magnetic susceptibility Biuret test Inorganic Chemistry Metal visual_art visual_art.visual_art_medium First transition series Physical chemistry Chelation Thermal stability Physical and Theoretical Chemistry Spectral data
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 31:1611-1621
ISSN:	1532-2440 0094-5714
Popis:	The present paper describes the synthesis and structural features of the polymeric chelates of glutarylbis(biuret) and suberylbis(biuret) with metals of the first transition series viz., Mn(II), Co(II), Ni(II), Cu(II) and Zn(II). The resulting polymeric complexes have been characterized on the basis of elemental analyses, electronic spectral and magnetic susceptibility studies. The nature of bonding has been further discussed on the basis of IR spectral data. A detailed thermal study of the polymeric chelates has been carried out to ascertain their thermal stability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fce3bc9499cc61b80bdd8f3c2210bbac https://doi.org/10.1081/sim-100107707 Zobrazit plný text záznamu Plný text ve formátu PDF