A Fourfold Benzodehydroannuleno-Fused Porphyrazine

Autor:	Clemens Bruhn, Rüdiger Faust, Fabian Körte
Rok vydání:	2015
Předmět:	Coupling (electronics) chemistry.chemical_classification Graphyne chemistry.chemical_compound Strain (chemistry) chemistry Acetylene Singlet oxygen Organic Chemistry Alkyne Porphyrazine Phenanthrene Photochemistry
Zdroj:	Synlett. 26:1620-1624
ISSN:	1437-2096 0936-5214
Popis:	Four benzodehydroannulene subunits were implemented on a dibenzoquinoxalinopoprhyrazine core using efficient palladium-mediated alkyne coupling and oxidative acetylene coupling on phenanthrene dione precursors. Despite the significant amount of strain in system, as evidenced by X-ray analysis of an immediate precursor, porphyrazine assembly leads to an extended model for N-doped graphyne with photosensitizing properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fcdd62a4a36037678064e8d01a5d6b8a https://doi.org/10.1055/s-0034-1378710 Zobrazit plný text záznamu