Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under neat conditions
| Autor: | Jun-Yi He, Ying-Wu Lin, Kai-Jian Liu, Zhong Cao, Tang-Yu Zeng, Jia-Le Zeng, Jia-Xi Tan, Weimin He, Shao-Feng Gong |
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| Rok vydání: | 2019 |
| Předmět: |
02 engineering and technology
General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Solvent Metal chemistry.chemical_compound Dual role chemistry 5-hydroxymethylfurfural visual_art visual_art.visual_art_medium Organic chemistry 2 5-Furandicarboxylic acid 0210 nano-technology |
| Zdroj: | Chinese Chemical Letters. 30:2304-2308 |
| ISSN: | 1001-8417 |
| Popis: | An eco-friendly and economical route for the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) with atmospheric dioxygen as the sole oxidant under acid-, base-, metal-, and external initiator-free conditions in minimal solvent was reported. In the present reaction, the 1,2-diethoxyethylane has a dual role: reaction medium and free-radical initiator. The FDCA easily crystallizes during the reaction and was simple purified via recrystallization to provide the pure FDCA. |
| Databáze: | OpenAIRE |
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