Synthesis, Stability, and (De)hydrogenation Catalysis by Normal and Abnormal Alkene- and Picolyl-Tethered NHC Ruthenium Complexes
| Autor: | Frederick P. Malan, Eric Singleton, Marilé Landman, Martin Albrecht, Petrus H. van Rooyen |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Alkene Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences 3. Good health Ruthenium Inorganic Chemistry Hydrogenation catalysis chemistry Cyclopentadienyl complex Polymer chemistry Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 38:2624-2635 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.9b00178 |
| Popis: | A series of p-cymene and cyclopentadienyl Ru(II)-aNHC complexes were synthesized from 2-methylimidazolium salts with either an N-bound alkenyl (1, 3) or picolyl tether (6, 7). The C(5)-Me substitut... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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