Investigation of the ternary phase diagram of mechanically alloyed FeCuAg

Autor:	E Ahlswede, N S Cohen, J D Wicks, Quentin A. Pankhurst
Rok vydání:	1997
Předmět:	Materials science Ternary numeral system Mössbauer effect Analytical chemistry chemistry.chemical_element Condensed Matter Physics Copper Amorphous solid Crystallography Differential scanning calorimetry chemistry General Materials Science Ball mill Phase diagram Solid solution
Zdroj:	Journal of Physics: Condensed Matter. 9:3259-3276
ISSN:	1361-648X 0953-8984
DOI:	10.1088/0953-8984/9/15/016
Popis:	The structural and magnetic properties of mechanically alloyed Fe - Cu - Ag at room temperature have been investigated using Mossbauer spectroscopy, x-ray diffraction and differential scanning calorimetry. The elements are naturally immiscible, but through prolonged and energetic ball milling (70 hours at 600 rpm) one can make metastable alloys, the structure of which depends on the elemental composition. In the binary Cu - Ag and Fe - Cu systems, crystalline single-phase solid solutions result, whereas in Fe - Ag the alloying is limited, with the product a mixture of elemental particles. In the ternary system it is possible to produce copper- and silver-rich single-phase fcc alloys, but not the equivalent bcc iron-based structure. As the proportions of the three elements become more equal, the resulting structure becomes highly disordered or amorphous. The composition range of this amorphous phase is different to that observed in sputtered Fe - Cu - Ag systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fc8726b6319761889fa0e36214a5e66c https://doi.org/10.1088/0953-8984/9/15/016 Zobrazit plný text záznamu