Methyl nitroacetate and 3-nitropropionate in the synthesis of hexahydropyrimidines and piperidines

Autor:	R. F. Talipov, R. Z. Biglova, T. V. Dokichev, N. Z. Baibulatova, R. R. Shakirov, N. M. Vlasova
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Primary (chemistry) Chemistry Organic Chemistry Formaldehyde Organic chemistry Mannich reaction 3-nitropropionate
Zdroj:	Chemistry of Heterocyclic Compounds. 44:43-49
ISSN:	1573-8353 0009-3122
Popis:	Treatment of methyl nitroacetate and 3-nitropropionate with formaldehyde and primary amines under Mannich reaction conditions gives 5-nitrohexahydropyrimidines. In the case of methyl nitroacetate both the 5-nitrohexahydropyrimidine and isomeric 3,5-di(methoxycarbonyl)-1-methyl-3,5-dinitropiperidines are formed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fc7e93f80dcdfebbd2239f9a24c704d7 https://doi.org/10.1007/s10593-008-0011-y Zobrazit plný text záznamu Plný text ve formátu PDF