Ethyl-4,4,4-trifluoroacetoacetate (ETFAA), a powerful building block for enantiopure chirons in trifluoromethyl-β-amino acid series

Autor:	Jean-Marc Paris, Jean-Christophe Plaquevent, Valérie Michaut, François Metz
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Trifluoromethyl Chemistry Stereochemistry Organic Chemistry Block (permutation group theory) Biochemistry Amino acid Inorganic Chemistry chemistry.chemical_compound Enantiopure drug Environmental Chemistry Moiety Organic chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Fluorine Chemistry. 128:889-895
ISSN:	0022-1139
Popis:	Herein are studied new transformations of ethyl-4,4,4-trifluoroacetoacetate (ETFAA), giving access to a series of enantiopure chirons bearing both a trifluoromethyl group and an amino moiety. The key intermediate is obtained optically pure by a resolution procedure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fc7baeeeea58738c593ae3b639742dde https://doi.org/10.1016/j.jfluchem.2007.03.007 Zobrazit plný text záznamu Full Text from ScienceDirect