Lead Ion‐Selective Polypyrrole Solid‐Contact Electrode Based on Crown Ether

Autor:	Koo-Chun Chung, Eun‐Jung Jang, Jihye Shim
Rok vydání:	2007
Předmět:	Working electrode Chemistry Biochemistry (medical) Clinical Biochemistry Inorganic chemistry Polypyrrole Biochemistry Reference electrode Glass electrode Analytical Chemistry law.invention Ion selective electrode chemistry.chemical_compound Quinhydrone electrode law Saturated calomel electrode Palladium-hydrogen electrode Electrochemistry Spectroscopy
Zdroj:	Analytical Letters. 40:3038-3049
ISSN:	1532-236X 0003-2719
DOI:	10.1080/00032710701646099
Popis:	The lead(II) ion selective solid‐contact electrode based on polypyrrole film, covered with a polyvinyl chloride membrane has been prepared. Polypyrrole film was used as a mediating layer of the solid‐contact electrode due to the conductivity. Crown ether has been used as ionophores in polyvinyl chloride cocktail solutions. This solid‐contact electrode based on benzo‐15‐crown‐5 exhibited Nernstian‐response within 30 s response time over concentration range, 1×10−1∼5×10−7 M. The selectivity of this electrode to other metal cations was comparatively good. This electrode showed much better results, such as detection range, slope, response time and reproducibility than conventional ion selective electrode and coated wire electrode.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fc76bb03ed36506b1453d64a689cb12e https://doi.org/10.1080/00032710701646099 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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