Highly Conductive Langmuir-Blodgett Films Based on Dialkyldimethylammonium-Metal(DMIT)2

Autor: Takumi Kawasaki, Hideaki Ohnishi, Yoshihito Okuma, Yasuhiro F. Miura, Michio Sugi
Rok vydání: 1999
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 337:365-368
ISSN: 1058-725X
DOI: 10.1080/10587259908023453
Popis: Structure and electrical conductivities of the mixed LB films of dioctadecyldimethylammonium-Au(dmit)2 (2C18-Au) and arachidic acid (C20) are studied with various mixing ratios. The in-plane conductivity at room temperature decreases with increasing the molar mixing ratio of C20. Both the as-deposited and electrochemically-oxidized LB films give sharp X-ray diffraction peaks at 2θ = 3.15° indicating a d-spacing of 2.8 nm which is identical to that of pure 2C18-Au system. It is suggested that the 2C18-Au complex forms an identical layered structure both in the pure and the mixed systems.
Databáze: OpenAIRE