Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions
| Autor: | A. V. Rotov, Elena A. Ugolkova, Aleksei A. Sidorov, Vadim V. Minin, N. V. Zauzolkova, Igor L. Eremenko, I. A. Apolonskaya, Mikhail A. Kiskin, Vladimir M. Novotortsev, Matvey V. Fedin, Grigory G. Aleksandrov, M. E. Nikiforova |
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| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_classification
Ligand Potassium Inorganic chemistry chemistry.chemical_element Salt (chemistry) General Chemistry Copper law.invention Metal chemistry.chemical_compound chemistry law visual_art Polymer chemistry Pyridine visual_art.visual_art_medium Carboxylate Electron paramagnetic resonance |
| Zdroj: | Russian Chemical Bulletin. 59:1186-1191 |
| ISSN: | 1573-9171 1066-5285 |
| DOI: | 10.1007/s11172-010-0221-1 |
| Popis: | The reaction of copper nitrate Cu(NO3)2·3H2O with potassium salt of 1,1-cyclohexanediacetic acid (H2CHDAA) in an EtOH-toluene mixture affords the polymeric complex {[(EtOH)2Cu2(CHDAA)2]·EtOHn (1). The addition of pyridine to the Cu(NO3)2·3H2O-K2CHDAA reaction system in an EtOH-MeCN mixture results in the isolation of the unusual octadecanuclear heterometallic cluster [K2(η1-H2O)6(η1-py)8Cu16-(η1-OH)2(μ4-CHDAA)16]·EtOH·MeCN·3H2O (2). In complex 2, the hexadecanuclear metal carboxylate dianion (η1-H2O)6(η1-py)8Cu16(η1-OH)2(μ4-CHDAA)16 acts as the metal-containing macropolycyclic ligand. The newly synthesized compounds 1 and 2 were characterized by X-ray diffraction and EPR. |
| Databáze: | OpenAIRE |
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