Electrochemistry and morphology of graphite negative electrodes containing silicon as capacity-enhancing electrode additive
| Autor: | Fabian Jeschull, Petr Novák, Simone Zürcher, Michael E. Spahr, Yuri Surace, Sigita Trabesinger |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Silicon General Chemical Engineering technology industry and agriculture chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Hysteresis chemistry Electrode Graphite Fade Composite material 0210 nano-technology Capacity loss Voltage |
| Zdroj: | Electrochimica Acta. 320:134602 |
| ISSN: | 0013-4686 |
| DOI: | 10.1016/j.electacta.2019.134602 |
| Popis: | In this study, the use of silicon as a capacity-enhancing electrode additive to graphite electrodes was investigated. Based on energy-density estimations, the silicon amount was restricted to less than 20 wt%. The viability of such graphite–Si electrode blends was evaluated with regard to their cycle-life in relation to the silicon content of the electrode, showing how Si content and capacity fade are correlated. The addition of Si gradually alters the electrode morphology as shown by electrode cross-section images, and is partly responsible for the progressive capacity loss. In addition, we also demonstrate how analysis of the voltage hysteresis can provide early indications of cell failure. To complete the picture, one graphite–Si formulation was evaluated in a full-cell setup. The electrochemical study of this 3-electrode setup is complemented by a charge-injection experiment that replenishes the Li inventory and serves to pinpoint the origins of capacity fading more accurately under the cycling conditions chosen. |
| Databáze: | OpenAIRE |
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