Synthesis of the spiroacetal fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113
Autor: | Hiromasa Kiyota, Hiroyuki Sakauchi, Shigefumi Kuwahara, Yuko Asamitsu, Yuko Shimizu, Mikiko Kojima, Emi Higashi, Minoru Izumi |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Heterocyclic Communications. 21:337-343 |
ISSN: | 2191-0197 0793-0283 |
DOI: | 10.1515/hc-2015-0193 |
Popis: | The spiroacetal [C(9)–C(20)] fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113, were prepared from a known bromo alcohol derived from (S)-citronellal, using thermodynamically controlled iodolactonization and spiroacetalization as the key steps. |
Databáze: | OpenAIRE |
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