Normal sulphites of metals

Autor: Saied M. El-Sayed, Kamal A. R. Salib, Salah B. El-Maraghy, Samy M. Abu El-Wafa
Rok vydání: 1989
Předmět:
Zdroj: Transition Metal Chemistry. 14:306-308
ISSN: 1572-901X
0340-4285
DOI: 10.1007/bf01098236
Popis: Normal sulphites of metals were prepared by the reaction of metal salts with sodium metabisulphite, in aqueous acid solutions, to prevent the formation of basic sulphites. Visible spectra and magnetic moments show that the transition metal sulphites have distorted octahedral structures. The i.r. spectra showed that the sulphite groups act as O-bonded bridging ligands linking the metal atoms in polymeric chains.
Databáze: OpenAIRE