A study of TiO2 binder-free paste prepared for low temperature dye-sensitized solar cells
Autor: | Inna Karatchevtseva, Gerri Triani, Klaudia Wagner, Jeremy H. Yune, David L. Officer |
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Rok vydání: | 2012 |
Předmět: |
Materials science
Mechanical Engineering Energy conversion efficiency Chemical modification Thermal treatment Condensed Matter Physics Ammonia chemistry.chemical_compound Dye-sensitized solar cell chemistry Chemical engineering Mechanics of Materials Electrode General Materials Science Fourier transform infrared spectroscopy Composite material Sol-gel |
Zdroj: | Journal of Materials Research. 28:488-496 |
ISSN: | 2044-5326 0884-2914 |
DOI: | 10.1557/jmr.2012.354 |
Popis: | A binder-free titania paste was prepared by chemical modification of an acidic TiO2 sol with ammonia. By varying the ammonia concentration, the viscosity of the acidic TiO2 suspension increased, thereby allowing uniform films to be cast. The photoelectrochemical performance of TiO2 electrodes, cast as single layers, was dependent on the thermal treatment cycle. Fourier transform infrared spectroscopy was used to characterize the extent of residual organics and found that acetates from the TiO2precursor preparation were retained within the electrode structure after thermal treatment at 150 °C. Electrodes of nominal thickness 4 μm produced an energy conversion efficiency as high as 5.4% using this simple thermal treatment. |
Databáze: | OpenAIRE |
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