Vapour-liquid equilibrium for tripropylene glycol + aromatic hydrocarbons binary systems: Measurements and modelling
| Autor: | Marilena Nicolae, Florin Oprea, Elena M. Fendu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Tripropylene glycol
General Chemical Engineering General Physics and Astronomy Binary number Thermodynamics 02 engineering and technology 010402 general chemistry 01 natural sciences Ethylbenzene Toluene 0104 chemical sciences chemistry.chemical_compound 020401 chemical engineering chemistry Non-random two-liquid model 0204 chemical engineering Physical and Theoretical Chemistry UNIFAC |
| Zdroj: | Fluid Phase Equilibria. 425:188-195 |
| ISSN: | 0378-3812 |
| DOI: | 10.1016/j.fluid.2016.05.032 |
| Popis: | Vapour-liquid equilibrium (VLE) data are reported for five binary systems involving aromatic hydrocarbons (toluene, ethylbenzene, o-xylene, m-xylene, and p-xylene) and tripropylene glycol (2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol). VLE data was determined by using a static method for the binary mixtures at temperatures within 305.15 K–496.15 K. The p-T-x experimental data obtained were correlated using the NRTL model, in order to obtain the binary interaction parameters for each mixture. We compared the T-x-y diagrams determined based on the NRTL resulted parameters with the diagrams calculated using the UNIFAC predictive model and IDEAL model. We observed differences between the T-x curves calculated with the NRTL model that includes the binary interaction parameters resulting from the experimental VLE data and the T-x curves calculated with UNIFAC predictive model and IDEAL model. |
| Databáze: | OpenAIRE |
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