Cyclodimerization of bicyclo[2.2.1]hepta-2,5-diene in the presence of rhodium-containing zeolite catalysts

Autor:	Kh. M. Minachev, N. F. Gol'dshleger, Ya. I. Isakov, B. I. Azbel, E. S. Shpiro
Rok vydání:	1994
Předmět:	chemistry.chemical_compound chemistry Diene Bicyclic molecule Norbornadiene chemistry.chemical_element General Chemistry Zeolite Selectivity Medicinal chemistry Cycloaddition Rhodium Catalysis
Zdroj:	Russian Chemical Bulletin. 43:1802-1808
ISSN:	1573-9171 1066-5285
Popis:	It has been shown that norbornadiene is dimerized in the presence of rhodium-containing zeolite catalysts, forming hexacyclic [4+2]dimers preferentially. The effect of the structure and the method of preparation and pretreatment of the catalysts on their activity and selectivity in norbornadiene cycloaddition was studied. The influence of the above parameters on the change in the electronic state of rhodium in the course of the reaction was also investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fbcee0bca295b271e198fddd402ed282 https://doi.org/10.1007/bf00696305 Zobrazit plný text záznamu Full text from SpringerLink