Cathodic reduction of benzil in acetone and in dichloromethane

Autor:	Gloria Quintanilla, Carina Bengtsson, Fructuoso Barba, Lena Arnold, Miriam Liebeck
Rok vydání:	2008
Předmět:	General Chemical Engineering Inorganic chemistry Electrochemistry Chloride Lithium perchlorate chemistry.chemical_compound chemistry Oxalyl chloride Electrophile medicine Acetone Benzil Dichloromethane medicine.drug
Zdroj:	Electrochimica Acta. 53:2674-2678
ISSN:	0013-4686
Popis:	The cathodic reduction of benzil has been carried out at a controlled potential on a mercury cathode in two different SSE (solvent-supporting-electrolyte) conditions: (a) acetone/lithium perchlorate in absence of electrophile where 2,3-diphenyl-5-methyl-furan and 1,2-diphenyl-2-hydroxy-1,4-pentanedione were obtained as main products and (b) dichloromethane/tetrabuthylammonium chloride with the addition of oxalyl chloride as electrophile, where a fast electron transfer took place.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fbcb8b7fe88541774eb415f091a5ac0a https://doi.org/10.1016/j.electacta.2007.07.016 Zobrazit plný text záznamu Full Text from ScienceDirect