Adsorption behavior of isocyanate/ethylenediamine tetraacetic acid-functionalized graphene oxides for Cu2+ removal
| Autor: | Liao Youwei, Huang Bin, Yu Yun, Ya-fei Kuang, Yang Yan, Yang Ningning |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Thermogravimetric analysis
Environmental Engineering Oxide Langmuir adsorption model Ethylenediamine 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Isocyanate 0104 chemical sciences chemistry.chemical_compound symbols.namesake Adsorption chemistry X-ray photoelectron spectroscopy Desorption symbols 0210 nano-technology Water Science and Technology Nuclear chemistry |
| Zdroj: | Water Science and Technology. 78:2459-2468 |
| ISSN: | 1996-9732 0273-1223 |
| DOI: | 10.2166/wst.2018.520 |
| Popis: | A special adsorption of Cu2+ removal is demonstrated using specifically functionalized graphene oxide (GO)/isocyanate (MDI) composites, on which ethylenediamine tetraacetic acid (EDTA) is grafted via amidation and carbamate reaction. The structure and morphology of GO and functionalized composites (EDTA/MDI/GO) were characterized by scanning electron microscope (SEM), Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Thermogravimetric analysis (TGA). This study investigated the adsorption and desorption behaviors of heavy metal cations and the effects of solution conditions such as pH on Cu2+ removal. The experimental results illustrated that after introducing EDTA and MDI into the GO, the maximum adsorption capacity reached 254.2 ± 10.4 mg/g within 180 min, obviously higher than the GO prepared without these additions (136.5 ± 7.2 mg/g). The EDTA/MDI/GO adsorption kinetics and equilibrium adsorption isotherm fitted the pseudo-second-order kinetic model (R2 = 0.995) and Langmuir isotherm model (R2 = 0.986) well, respectively. Furthermore, EDTA/MDI/GO also displayed good reusability for the efficient removal of Cu2+ after being washed with HCl, suggesting potential application in Cu2+ cleanup. |
| Databáze: | OpenAIRE |
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