NaI/KI/NH4I and TBHP as powerful oxidation systems: use in the formation of various chemical bonds

Autor:	Bhaskar Ganguly, Prasanjit Ghosh, Sajal Das
Rok vydání:	2021
Předmět:	Green chemistry chemistry.chemical_compound Chemical bond Chemistry Organic Chemistry Molecule Organic synthesis Physical and Theoretical Chemistry Biochemistry Combinatorial chemistry
Zdroj:	Organic & Biomolecular Chemistry. 19:2146-2167
ISSN:	1477-0539 1477-0520
DOI:	10.1039/d0ob02169e
Popis:	In modern organic synthesis, the execution of reactions in the absence of expensive transition metals has received significant attention from the view-point of green chemistry and sustainable development. As a consequence, the combination of MI-TBHP as an oxidation system (M = Na, K, NH4) has opened a new avenue with significant impact for the succinct synthesis of complex heterocycle molecules via the construction of various chemical bonds [C-X (X = C, N, S, O), N-X (X = N, P) and S-N]. This comprehensive review article delineates the progress of recent developments in this emerging area, with an in-depth discussion on the substrate scope, limitations and proper mechanistic underpinnings. We hope this review will highlight the great potential of this MI-TBHP as a powerful oxidation system and inspire researchers to conduct further endeavors in this domain.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fbaaccc1acff43255e0956b2f6b6cb66 https://doi.org/10.1039/d0ob02169e Zobrazit plný text záznamu