Mn(5−n)/2HnPMOV2 as re-oxidant of palladium(II) in solid Wacker catalysts

Autor: Donalita Dudko, Krystyna Nowińska
Rok vydání: 1997
Předmět:
Zdroj: Reaction Kinetics and Catalysis Letters. 61:187-192
ISSN: 1588-2837
0133-1736
DOI: 10.1007/bf02477534
Popis: Managanese salts of heteropoly acids (HPA) containing molybdenum and vanadium as poly atoms appeared to be active co-catalysts of palladium(II) in heterogeneous Wacker systems employed for ethene to acetaldehyde oxidation. The ethene conversion and the catalyst lifetime depend on the number of HPA protons replaced with Mn2+ cations.
Databáze: OpenAIRE