Mn(5−n)/2HnPMOV2 as re-oxidant of palladium(II) in solid Wacker catalysts
Autor: | Donalita Dudko, Krystyna Nowińska |
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Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Reaction Kinetics and Catalysis Letters. 61:187-192 |
ISSN: | 1588-2837 0133-1736 |
DOI: | 10.1007/bf02477534 |
Popis: | Managanese salts of heteropoly acids (HPA) containing molybdenum and vanadium as poly atoms appeared to be active co-catalysts of palladium(II) in heterogeneous Wacker systems employed for ethene to acetaldehyde oxidation. The ethene conversion and the catalyst lifetime depend on the number of HPA protons replaced with Mn2+ cations. |
Databáze: | OpenAIRE |
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