Reaction of 1,4-pentadiyne with diethylaminotrimethylstannane

Autor:	Christoph Bihlmayer, Bernd Wrackmeyer
Rok vydání:	1984
Předmět:	Chemistry Organic Chemistry Nuclear magnetic resonance spectroscopy Biochemistry Medicinal chemistry Nmr data Enamine Inorganic Chemistry chemistry.chemical_compound Product (mathematics) Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Aliphatic compound
Zdroj:	Journal of Organometallic Chemistry. 266:33-36
ISSN:	0022-328X
DOI:	10.1016/0022-328x(84)80107-2
Popis:	The reaction between 1,4-pentadiyne and diethylaminotrimethylstannane leads predominantly to ( E )-2-diethylamino-4-trimethylstannyl-2,4-pentaenyne (with either a 1/1 or 1/2 mol ratio of 1,4-pentadiyne and diethylaminotrimethylstannane). With 1/2 stoicheiometry 1,1,5-tris(trimethylstannyl)penta-1,2-dien-4-yne is formed as a minor product. 13 C and 119 Sn NMR data are reported.
Databáze:	OpenAIRE
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