Correlation of Solute Transfer Into Toluene and Ethylbenzene from Water and from the Gas Phase Based on the Abraham Model

Autor:	Connie Shen, Matthew Loera, William E. Acree, Amanda N. Quay, Vicky Chou, Timothy W. Stephens, Michael H. Abraham, Anastasia Wilson
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Partition coefficient chemistry.chemical_compound Transfer (group theory) chemistry Solvation Thermodynamics Aromatic hydrocarbon Toluene Ethylbenzene Gas phase
Zdroj:	The Open Thermodynamics Journal. 5:104-121
ISSN:	1874-396X
DOI:	10.2174/1874396x01105010104
Popis:	Experimental data have been compiled from the published literature on the partition coefficients of solutes and vapors into ethylbenzene and toluene at 298 K. The logarithms of the water-to-ethylbenzene and water-to-toluene partition coefficients, log P, and gas-to-ethylbenzene and gas-to-toluene partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived mathematical expressions described the observed log P and log K data for the two aromatic hydrocarbon solvents to within average deviations of 0.13 log units or less.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb8974e3230fa63c713814395c73d845 https://doi.org/10.2174/1874396x01105010104 Zobrazit plný text záznamu