Disproportional ferric sulfide catalysts for coal liquefaction

Autor:	John W. Zondlo, C. D. Stinespring, W. R. Stewart, and A. H. Stiller, Dady B. Dadyburjor, J. P. Wann
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Sulfide Chemistry General Chemical Engineering Inorganic chemistry Energy Engineering and Power Technology Liquefaction Disproportionation engineering.material Coal liquefaction Catalysis Fuel Technology engineering medicine Ferric Pyrite Pyrrhotite medicine.drug
Zdroj:	Energy & Fuels. 8:19-24
ISSN:	1520-5029 0887-0624
Popis:	Above 5 °C, ferric sulfide disproportionates into mixtures of pyrite (PY), pyrrhotite (PH), and elemental S, with the relative amounts depending upon disproportionation temperature and time. The PH/PY mixtures are used as catalysts for coal liquefaction, with the optimum mixture corresponding to disproportionation at 200 °C for 1 h. Reactions of Fe during disproportionation and liquefaction are postulated and confirmed by AA, AES, and XRD. The iron loading has a nonlinear effect on conversion and yield
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb83e14005c81da3d84205dffd09fb9d https://doi.org/10.1021/ef00043a003 Zobrazit plný text záznamu